Vector vs. Raster Art & File Format Reference
"Never say never!" Yes, there are exceptions to any rule, but, generally speaking, you're safe to to go by my NEVER's and ALWAYS's.
Download a print-friendly PDF here.
Never Vector
.jpg
.png
.psd*
.tif
.gif
.bmp
May Be Vector
.eps
.ai
.svg
.pdf
Vector art MUST be one of these formats.
BUT, confusingly, raster art can also be saved as any of these.
To check if something is truly vector, zoom in close - if you see pixelation at all, it's not vector.